Crystal structures and nitrosation reactions of triazido complexes of chromium(III)

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Crystal structures and nitrosation reactions of triazido complexes of chromium(III). / Døssing, Anders Rørbæk; Kadziola, Anders.

In: Journal of Coordination Chemistry, Vol. 61, No. 11, 2008, p. 1671-1677.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Døssing, AR & Kadziola, A 2008, 'Crystal structures and nitrosation reactions of triazido complexes of chromium(III)', Journal of Coordination Chemistry, vol. 61, no. 11, pp. 1671-1677.

APA

Døssing, A. R., & Kadziola, A. (2008). Crystal structures and nitrosation reactions of triazido complexes of chromium(III). Journal of Coordination Chemistry, 61(11), 1671-1677.

Vancouver

Døssing AR, Kadziola A. Crystal structures and nitrosation reactions of triazido complexes of chromium(III). Journal of Coordination Chemistry. 2008;61(11):1671-1677.

Author

Døssing, Anders Rørbæk ; Kadziola, Anders. / Crystal structures and nitrosation reactions of triazido complexes of chromium(III). In: Journal of Coordination Chemistry. 2008 ; Vol. 61, No. 11. pp. 1671-1677.

Bibtex

@article{236b62f0bc8711dd8e02000ea68e967b,
title = "Crystal structures and nitrosation reactions of triazido complexes of chromium(III)",
abstract = "  The two triazido chromium(III) complexes [Cr(tame)(N3)3]×H2O (1) and [Cr(tacn)(N3)3] (2) (tame  = 1,1,1-tris(aminomethyl)ethane and tacn = 1,4,7-triazacyclononane) have been prepared and characterized by single-crystal X-ray crystallography at 122 K. The crystal structure of 1 is monoclinic, space group P21/c, with a = 9.2460(9), b = 11.0500(11), c = 13.1980(9) {\AA}, b = 97.244(7)° with four formula units in the cell. The crystal structure of 2 is triclinic, space group P , with a = 7.698(4), b = 8.5800(6), c = 10.236(3) {\AA}, a = 89.497(15), b = 83.70(2), g = 72.83(2)° with two formula units in the cell. The reactions between NOBF4  and 1 or 2 in acetonitrile give [Cr(tame)(NCCH3)3](BF4)3, and [Cr(tacn)(NCCH3)3](BF4)3, respectively. ",
keywords = "Faculty of Science",
author = "D{\o}ssing, {Anders R{\o}rb{\ae}k} and Anders Kadziola",
note = "Paper id:: 10.1080/00958970701617793",
year = "2008",
language = "English",
volume = "61",
pages = "1671--1677",
journal = "Journal of Coordination Chemistry",
issn = "0095-8972",
publisher = "Taylor & Francis",
number = "11",

}

RIS

TY - JOUR

T1 - Crystal structures and nitrosation reactions of triazido complexes of chromium(III)

AU - Døssing, Anders Rørbæk

AU - Kadziola, Anders

N1 - Paper id:: 10.1080/00958970701617793

PY - 2008

Y1 - 2008

N2 -   The two triazido chromium(III) complexes [Cr(tame)(N3)3]×H2O (1) and [Cr(tacn)(N3)3] (2) (tame  = 1,1,1-tris(aminomethyl)ethane and tacn = 1,4,7-triazacyclononane) have been prepared and characterized by single-crystal X-ray crystallography at 122 K. The crystal structure of 1 is monoclinic, space group P21/c, with a = 9.2460(9), b = 11.0500(11), c = 13.1980(9) Å, b = 97.244(7)° with four formula units in the cell. The crystal structure of 2 is triclinic, space group P , with a = 7.698(4), b = 8.5800(6), c = 10.236(3) Å, a = 89.497(15), b = 83.70(2), g = 72.83(2)° with two formula units in the cell. The reactions between NOBF4  and 1 or 2 in acetonitrile give [Cr(tame)(NCCH3)3](BF4)3, and [Cr(tacn)(NCCH3)3](BF4)3, respectively.

AB -   The two triazido chromium(III) complexes [Cr(tame)(N3)3]×H2O (1) and [Cr(tacn)(N3)3] (2) (tame  = 1,1,1-tris(aminomethyl)ethane and tacn = 1,4,7-triazacyclononane) have been prepared and characterized by single-crystal X-ray crystallography at 122 K. The crystal structure of 1 is monoclinic, space group P21/c, with a = 9.2460(9), b = 11.0500(11), c = 13.1980(9) Å, b = 97.244(7)° with four formula units in the cell. The crystal structure of 2 is triclinic, space group P , with a = 7.698(4), b = 8.5800(6), c = 10.236(3) Å, a = 89.497(15), b = 83.70(2), g = 72.83(2)° with two formula units in the cell. The reactions between NOBF4  and 1 or 2 in acetonitrile give [Cr(tame)(NCCH3)3](BF4)3, and [Cr(tacn)(NCCH3)3](BF4)3, respectively.

KW - Faculty of Science

M3 - Journal article

VL - 61

SP - 1671

EP - 1677

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

SN - 0095-8972

IS - 11

ER -

ID: 8778165